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A Pictorial Approach to Molecular Bonding by John G Verkade: Used
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N.º de artículo de eBay:364964951407
Última actualización el 03 ago 2025 09:47:52 H.EspVer todas las actualizacionesVer todas las actualizaciones
Características del artículo
- Estado
- Book Title
- A Pictorial Approach to Molecular Bonding
- Publication Date
- 1986-09-24
- Pages
- 282
- ISBN
- 9780387962719
Acerca de este producto
Product Identifiers
Publisher
Springer New York
ISBN-10
0387962719
ISBN-13
9780387962719
eBay Product ID (ePID)
123798
Product Key Features
Number of Pages
282 Pages
Language
English
Publication Name
Pictorial Approach to Molecular Bonding
Publication Year
1986
Subject
Chemistry / Physical & Theoretical, Chemistry / Inorganic
Type
Textbook
Subject Area
Science
Format
Hardcover
Dimensions
Item Weight
20.8 Oz
Additional Product Features
Intended Audience
Scholarly & Professional
LCCN
85-030272
TitleLeading
A
Dewey Edition
19
Number of Volumes
1 vol.
Illustrated
Yes
Dewey Decimal
541.2/24
Table Of Content
1 The Orbital Picture for Bound Electrons.- 1.1 Traveling and Standing Waves.- 1.2 Wave Energy and Interference.- 1.3 Electron Orbitals.- 1.4 Normalization and Orthogonality.- 1.5 Systems with Many Electrons.- 1.6 Flexibility of Orbital Sets.- 2 Atomic Orbitals.- 2.1 Shapes of Canonical Orbitals.- 2.2 Sizes of Canonical Orbitals.- 2.3 Energies of Canonical AOs.- 2.4 Hybrid Orbitals.- 2.5 Hybrid Orbitals through s-p Mixing.- 2.6 Equivalent s1p1 Hybrid Orbitals.- 2.7 Equivalent sp2 Hybrid Orbitals.- 2.8 Equivalent sp3 Hybrid Orbitals.- 2.9 Intermediate Hybrid Orbitals.- 3 Diatomic Molecules.- 3.1 Molecule Formation and Motions.- 3.2 Generator and Molecular Orbitals.- 3.3 Generator Orbitals and Molecular Motions.- 3.4 Bond Strengths.- 3.5 Heteronuclear Diatomic Molecules.- 3.6 Localized MOs for Diatomic Molecules.- 4 Linear Triatomic Molecules.- 4.1 Linear FHF-.- 4.2 FXeF.- 4.3 OCO.- 4.4 Vibrational Modes for Linear Triatomics.- 5 Triangular and Related Molecules.- 5.1 H3+.- 5.2 N3+.- 5.3 Electron Dash Structures and Molecular Geometry.- 5.4 BF3.- 6 Bent Triatomic Molecules.- 6.1 H2O.- 6.2 NO2-.- 7 Polygonal Molecules.- 7.1 Te42+.- 7.2 c-C4 H4.- 7.3 c-C5H5-.- 7.4 c-C6H6, c-C 7H 7+, c-C8H82-.- 8 Octahedral and Related Molecules.- 8.1 ICl4-.- 8.2 BrF5.- 8.3 B5H9.- 8.4 PF6-.- 8.5 Octahedral Transition Metal Complexes-- Some Special Considerations.- 8.6 CoF 63- and Co[P(OCH3)3]63+.- 8.7 B6H62-.- 8.8 Mo6 Cl 84+.- 9 Tetrahedral and Related Molecules.- 9.1 PnH3.- 9.2 P4.- 9.3 CH4.- 9.4 PO43-.- 9.5 VCl4-.- 10 Bipyramidal and Related Molecules.- 10.1 BrF3.- 10.2 SF4.- 10.3 B5H52-.- 10.4 PF5.- 10.5 IF7.- 11 Prismatic Molecules.- 11.1 C6H6 (Prismane).- 11.2 C8H8 (Cubane).- 11.3 (?5-C5H5)2Fe.- Appendix I Symmetry, Molecular Orbitals, and Generator Orbitals.- Appendix II A Kit forVisualizing MOs in Three Dimensions.- Appendix III Hybrid GOs and Non-Cooperating Central Atoms.- Appendix IV Calculating the Angles for Conal Nodes.- Appendix V A Summary of Uses for Generator Orbitals.
Synopsis
With the development of accurate molecular calculations in recent years, useful predictions of molecular electronic properties are currently being made. It is therefore becoming increasingly important for the non-theoretically oriented chemist to appreciate the underlying principles governing molecular orbital formation and to distinguish them from the quantitative details as- sociated with particular molecules. It seems highly desirable then that the non- theoretician be able to deduce results of general validity without esoteric mathematics. In this context, pictorial reasoning is particularly useful. Such an approach is virtually indispensable if bonding concepts are to be taught to chemistry students early in their careers. Undergraduate chemistry majors typically find it difficult to formulate molecular orbital schemes, especially delocalized ones, for molecules more complicated than diatomics. The major reason for this regrettable situation is the general impracticability of teaching group theory before students take organic and inorganic courses, wherein the applications of these concepts are most beneficial. Consequently many students graduate with the misconcep- tion that the ground rules governing bonding in molecules such as NH3 are somehow different from those which apply to aromatic systems such as C H - 6 6 Conversely, seniors and many graduate students are usually only vaguely, if at all, aware that sigma bonding (like extended pi bonding) can profitably be described in a delocalized manner when discussing the UV-photoelectron spectrum of CH, for example., With the development of accurate molecular calculations in recent years, useful predictions of molecular electronic properties are currently being made. It is therefore becoming increasingly important for the non-theoretically oriented chemist to appreciate the underlying principles governing molecular orbital formation and to distinguish them from the quantitative details as sociated with particular molecules. It seems highly desirable then that the non theoretician be able to deduce results of general validity without esoteric mathematics. In this context, pictorial reasoning is particularly useful. Such an approach is virtually indispensable if bonding concepts are to be taught to chemistry students early in their careers. Undergraduate chemistry majors typically find it difficult to formulate molecular orbital schemes, especially delocalized ones, for molecules more complicated than diatomics. The major reason for this regrettable situation is the general impracticability of teaching group theory before students take organic and inorganic courses, wherein the applications of these concepts are most beneficial. Consequently many students graduate with the misconcep tion that the ground rules governing bonding in molecules such as NH3 are somehow different from those which apply to aromatic systems such as C H * 6 6 Conversely, seniors and many graduate students are usually only vaguely, if at all, aware that sigma bonding (like extended pi bonding) can profitably be described in a delocalized manner when discussing the UV-photoelectron spectrum of CH , for example.
LC Classification Number
QD146-197
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- m***m (2307)- Votos emitidos por el comprador.Últimos 6 mesesCompra verificadaI’m thrilled with my recent purchase . The website was user-friendly, and the product descriptions were accurate. Customer service was prompt and helpful, answering all my questions. My order arrived quickly, well-packaged, and the product exceeded my expectations in quality. I’m impressed with the attention to detail and the overall experience. I’ll definitely shop here again and highly recommend from this seller to others. Thank you for a fantastic experience!
- a***n (51)- Votos emitidos por el comprador.Últimos 6 mesesCompra verificadaMistakenly ordered a paperback that I thought was a hardcover, not sellers fault; it was described properly on the listing. Seller still processed a refund the day I went to return the item and let me keep the item anyway. A+++ service. Book arrived quickly in great condition and for a great price. Thank you so much! Amazing seller!
- n***c (95)- Votos emitidos por el comprador.Últimos 6 mesesCompra verificadaseller was communicative about my shipment, media mail took a while and tracking wasn't updated frequently, but seller communicated to me very quickly on status. the item came new and wrapped as described, though the packaging in it was packed wasn't sturdy and falling apart when it got to me.
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AlibrisBooks
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Votos de vendedor (514.743)
- m***m (2307)- Votos emitidos por el comprador.Últimos 6 mesesCompra verificadaI’m thrilled with my recent purchase . The website was user-friendly, and the product descriptions were accurate. Customer service was prompt and helpful, answering all my questions. My order arrived quickly, well-packaged, and the product exceeded my expectations in quality. I’m impressed with the attention to detail and the overall experience. I’ll definitely shop here again and highly recommend from this seller to others. Thank you for a fantastic experience!
- a***n (51)- Votos emitidos por el comprador.Últimos 6 mesesCompra verificadaMistakenly ordered a paperback that I thought was a hardcover, not sellers fault; it was described properly on the listing. Seller still processed a refund the day I went to return the item and let me keep the item anyway. A+++ service. Book arrived quickly in great condition and for a great price. Thank you so much! Amazing seller!
- n***c (95)- Votos emitidos por el comprador.Últimos 6 mesesCompra verificadaseller was communicative about my shipment, media mail took a while and tracking wasn't updated frequently, but seller communicated to me very quickly on status. the item came new and wrapped as described, though the packaging in it was packed wasn't sturdy and falling apart when it got to me.