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Oxidation Numbers and Oxidation States. Jorgensen 9783642877605 Free Shipping<|
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Características del artículo
- Estado
- PublishedOn
- 2012-04-29
- Title
- Oxidation Numbers and Oxidation States
- Artist
- Not Specified
- ISBN
- 9783642877605
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Product Information
The correlation of spectroscopic and chemical investigations in recent years has been highly beneficial of many reasons. Around 1950, no valid explanation was available of the colours of compounds of the five tran sition groups. Later, it was possible to identify the excited levels with those expected for an electron configuration with adefinite number of electrons in the partly filled shell. I t is not generally recognized that this is equivalent to determining spectroscopic oxidation states related to the preponderant electron configuration and not to estimates of the fractional atomic charges. This brings in an entirely different type of description than the formal oxidation numbers used for characterizing compounds and reaction schemes. However, it must be realized that collectively oxidized ligands, formation of cluster-complexes and catenation may prevent the oxidation state from being well-defined. The writer would like to express his gratitude to many, but first of all to DR. CLAUS SCHAEFFER, University of Copenhagen, who is the most efficient group-theoretical engineer known to the writer; his comments and discussions have been highly valuable. The writer's colleague, Pro fessor FAUSTO CALDERAZZO (now going to the University of Pisa) has been most helpful in metallo-organic questions. Thanks are also due to Professors E. RANcKE-MADsEN and K. A. JENSEN for correspondence and conversations about formal oxidation numbers.
Product Identifiers
Publisher
Springer-Verlag Berlin AND Heidelberg Gmbh & Co. KG
ISBN-13
9783642877605
eBay Product ID (ePID)
209624127
Product Key Features
Number of Pages
292 Pages
Publication Name
Oxidation Numbers and Oxidation States
Language
English
Subject
Chemistry
Publication Year
2012
Type
Textbook
Series
Molekulverbindungen Und Koordinationsverbindungen in Einzeldarstellungen
Format
Paperback
Dimensions
Item Height
235 mm
Item Weight
462 g
Item Width
155 mm
Additional Product Features
Country/Region of Manufacture
Germany
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