Edition DescriptionRevised edition
SynopsisProperties of Polymers: Their Correlation with Chemical Structure; Their Numerical Estimation and Prediction from Additive Group Contributions summarizes the latest developments regarding polymers, their properties in relation to chemical structure, and methods for estimating and predicting numerical properties from chemical structure. In particular, it examines polymer electrical properties, magnetic properties, and mechanical properties, as well as their crystallization and environmental behavior and failure. The rheological properties of polymer melts and polymer solutions are also considered. Organized into seven parts encompassing 27 chapters, this book begins with an overview of polymer science and engineering, including the typology of polymers and their properties. It then turns to a discussion of thermophysical properties, from transition temperatures to volumetric and calorimetric properties, along with the cohesive aspects and conformation statistics. It also introduces the reader to the behavior of polymers in electromagnetic and mechanical fields of force. The book covers the quantities that influence the transport of heat, momentum, and matter, particularly heat conductivity, viscosity, and diffusivity; properties that control the chemical stability and breakdown of polymers; and polymer properties as an integral concept, with emphasis on processing and product properties. Readers will find tables that give valuable (numerical) data on polymers and include a survey of the group contributions (increments) of almost every additive function considered. This book is a valuable resource for anyone working on practical problems in the field of polymers, including organic chemists, chemical engineers, polymer processers, polymer technologists, and both graduate and PhD students., Paperback. As a source of data and for estimations of properties to be expected this book is now widely used all over the world. This Third Edition is thoroughly revised and updated. Its objectives, as for the previous two editions, are to correlate properties with chemical structure and to describe methods that permit the estimation and prediction of numerical properties from chemical structure, i.e. nearly all properties of the solid, liquid and dissolved states of polymers.New are chapters and sub-chapters discussing extended chain polymers, liquid crystal polymers and high performance polymers, De Gennes' scaling concept of polymer solutions, physical ageing, acoustic properties, the dual-mode permeation theory, the decomposition temperature and polymer reinforcing constructions. The chapters and sub-chapters on molecular mass distribution, glass and crystalline-melt temperatures, equations of state and on failure mechanisms have been greatly extende