Advances in Polymer Science Ser.: Statistical, Gradient and Segmented Copolymers

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N.º de artículo de eBay:126842464199
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Características del artículo

Estado
En muy buen estado: Libro que se ha leído y que no tiene un aspecto nuevo, pero que está en un ...
Level
Advanced
ISBN
9783540432449
Categoría

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Product Identifiers

Publisher
Springer Berlin / Heidelberg
ISBN-10
3540432442
ISBN-13
9783540432449
eBay Product ID (ePID)
2346350

Product Key Features

Number of Pages
Xii, 192 Pages
Language
English
Publication Name
Statistical, Gradient and Segmented Copolymers by Controlled/Living Radical Polymerizations
Subject
Materials Science / General, Textiles & Polymers, Physics / Condensed Matter, Physics / Polymer, Chemistry / Physical & Theoretical
Publication Year
2002
Type
Textbook
Subject Area
Technology & Engineering, Science
Author
Krzysztof Matyjaszewski, Kelly A. Davis
Series
Advances in Polymer Science Ser.
Format
Hardcover

Dimensions

Item Weight
36.7 Oz
Item Length
9.3 in
Item Width
6.1 in

Additional Product Features

Intended Audience
Scholarly & Professional
LCCN
2002-512934
Dewey Edition
21
Series Volume Number
159
Number of Volumes
1 vol.
Illustrated
Yes
Dewey Decimal
547.7 s 547/.28
Table Of Content
Statistical, Gradient, Block, and Graft Copolymers by Controlled/Living Radical Polymerizations.- Statistical Copolymers.- Linear Block Copolymers.- Other Chain Architectures.- Overall Summary.
Synopsis
The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions cannot be excluded completely, they are limited in their extent and consequently the mol ecular weight is controlled, the polydispersity index is small and functionalities can be attached to the macromolecules. These features are indicative of the real isation of well defined polymer architectures such as block copolymers, star shaped and comb shaped copolymers.
LC Classification Number
TA455.P58-.P585

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